The “traditional” tools of time series analysis (acf’s, spectral analysis) may find no evidence that we could use a linear model, but the data may still not be independent.
Portmanteau tests for non-linear dependence have been developed.
The simplest is Ramsey’s RESET test, which took the form:
Here the dependent variable is the residual series and the independent variables are the squares, cubes, …, of the fitted values.
Many other non-linearity tests are available - e.g., the BDS and bispectrum test
BDS is a pure hypothesis test. That is, it has as its null hypothesis that the data are pure noise (completely random)
It has been argued to have power to detect a variety of departures from randomness – linear or non-linear stochastic processes, deterministic chaos, etc)