Physical review volume 05, number january 15, 1957



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1957Diffusion and Electrical Behavior of Zinc in Silicon

TRIPLETS

In another context the problem of triplets has been considered before by Fuoss and Kraus20 who examined the interaction of two similar singly charged ions with a third singly charged ion of opposite sign. The triplet so constituted bore a net charge. We shall consider the interaction of two singly charged positive lithium ions with one doubly charged negative zinc. Since this triplet is neutral, the phenomena associated with it are quite different from those of the charged triplet.
Two stages of reaction may be distinguished. In the first a charged pair involving one lithium and one zinc is formed:
Li++Zn^= [Li+Zn=]. (2.1)

1!W. C. Dunlap, Jr., Phys. Rev. 86, 615(A) (1952); C. S. Fuller, Phys. Rev. 86, 136 (1952).

2 J. A. Burton, Physica 20, 845-854 (1954).

3 W. C. Dunlap, Jr., Phys. Rev. 96, 42 (1954).

4 Atom Movements (American Society for Metals, Cleveland,

5Ohio, 1951), p. 39.

6 Analysis showed the Zn to be at least 99.999% pure.

7 J. P. Coughlin, Bulletin of the Bureau of Mines No, 542, 1954.

8 M. B. Prince, Phys. Rev. 93, 1204 (1954).

9 F. J. Morin and J. P. Maita, Phys. Rev. 96, 28 (1954).

10 Recent observations on the influence of dislocations on the diffusion of Cu in Ge suggest that variations in crystal perfection may also be a factor.

11 Kaiser, Keck, and Lange, Phys. Rev. 101, 1264 (1956).

12 Even cleaning the specimens of rotated silicon by heating to glowing in vacuum did not provide uniform surface alloying of Zn although more local alloying occurred.

13(to be published).

14 F. van der Maesen and J. A. Brenkman, J. Electrochem. Soc.

15102, 229 (1955). A. W. Tweet and C. J. Gallagher, Phys. Rev.

16103, 828 (1956); C. S. Fuller and J. A. Ditzenberger, Phys. Rev.

17 Reiss, Fuller, and Pietruszkiewicz, J. Chern. Phys. 25, 650 (1956).

18 Reiss, Fuller, and Morin, Bell System Tech. J. 35, 535 (1956).

19 W. W. Tyler and H. H. Woodbury, Phys. Rev. 100, 1259(A) (1955).

20 R. M. Fuoss and C. A. Kraus, J. Am. Chern. Soc. 55, 2387 (1933).






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