Scheme 3: Mass spectral fragmentation pattern of phenyl substituted N-Phenylacetylmorpholine amides.
CONCLUSION In summary, the mass spectral fragmentation patterns of these amies were found to be unique and depends on the
substitution on both the phenyl ring and amines. These fragmentation patterns are useful for unambiguous identification
of these amides after their GC MS analysis.
ACKNOWLEDGEMENTS The authors thank Head, Syntheic Chemistry Division and Director, Defence Reserach and Development Establishment
(DRDE), Gwalior for his keen support and encouragement.
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N
O
O
H
HN
O
-87
C
H
132
C
O
-CHO
-29
103
C
N
O
O
114
C
N
O
O
H
N
O
86
-CO
-28
105
Base Peak
CH
2
Me
Me
Me
219
H
N
70
-16
-28
42
Gupta et al Der Chemica Sinica, 2017, 8(1):218-222