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P a g e
principle
一
polymerisation
一
underlies the creation of a huge range of plastics by the
chemical industry.
C
The first plastic was developed as a result of a competition in the USA. In the 1860s,
$10,000 was offered to anybody
who could replace ivory
— supplies of which were
declining
— with something equally good as a material for making billiard balls. The prize
was won by John Wesley Hyatt with a material called celluloid. Celluloid was made by
dissolving cellulose, a carbohydrate
derived from plants, in a solution of camphor
dissolved in ethanol. This new material rapidly found uses in the manufacture of products
such as knife handles, detachable collars and cuffs, spectacle frames and photographic
film. Without celluloid, the film industry could never have got off the ground at the end of
the 19th century.
D
Celluloid can be repeatedly softened and reshaped by heat, and is known as a
thermoplastic. In 1907 Leo Baekeland, a Belgian chemist working in the USA
,
invented
a different kind of plastic by causing phenol and formaldehyde to react together.
Baekeland called the material Bakelite, and it was the first of the thermosets' plastics that
can be cast and moulded while hot, but cannot be softened by heat and reshaped once
they have set.
Bakelite was a good insulator, and was resistant to water, acids and
moderate heat. With these properties it was soon being
used in the manufacture of
switches, household items, such as knife handles, and electrical components for cars.
E
Soon chemists began looking for other small molecules that could be strung together
to make polymers. In the 1930s, British chemists discovered that the gas ethylene would
polymerise under heat and pressure to form a thermoplastic they called polythene.
Polypropylene followed in the 1950s. Both were used to make bottles, pipes and plastic
bags. A small change in the starting material
一
replacing a hydrogen atom in ethylene
with a chlorine atom
— produced PVC (polyvinyl chloride)
,
a hard,
fireproof plastic
suitable for drains and gutters. And by adding certain chemicals, a soft form of PVC could
be produced, suitable as a substitute for rubber in items such as waterproof clothing. A
closely related plastic was Teflon, or PTFE (polytetrafluoroethylene). This had a very low
coefficient of friction, making it ideal for bearings, rollers, and non-stick frying pans.