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II INTERNATIONAL SCIENTIFIC CONFERENCE OF YOUNG RESEARCHERS 

144 

 Qafqaz University                         

          18-19 April 2014, Baku, Azerbaijan 

functional active groups and obtain phosphorus-containing organic compounds by the reaction of chlorophosphorylation 

[1]. FNBR polymer sorbents don’t solve in any solvent and the formation of nanoparticles have gone on the -PO(OH)

2

 

functional active groups. The preparation of samples were carried out by multicyclic processing of FNBR polymer sorbents 

with 0,1 M NiSO

4

 × 7H

2

O and 0,1 M Na

2

S aqueous solution and the number of cycle was five. After every stage, samples 

were washed with distillation water to remove unexchanged ions and air-dried. In obtaining of nanoparticles the nucleation 

process occurred in the first stage and grow of nanoparticles occurred after first stage. The FNBR polymer sorbents was 

used as stabilizing agent for formation nickel sulfide (NiS) nanoparticles. 

Synthesis of semiconductor nanoparticles NiS, into FNBR polymer matrix was carried out by multicyclic processing of 

polymer sorbents with sodium sulphide and metal salt solution. The reaction was undertaken at room temperature.  

The obtained nanoparticles were characterized by X-ray diffraction (XRD) using a Bruker D2 Phaser Advance X-ray 

diffractometer with Cu Ka irradiation (k = 1.54060 Е). By X-ray diffraction (XRD) study we determined the crystallite size 

and structural properties of NiS nanoparticles. The NiS nanoparticles exhibit hexagonal phase. The particle size for NiS 

nanoparticles is found to be about 12Å =1,2nm. Hkl=1,0,0. It is well known that the average diameter of the nickel sulfide 

nanocrystallites is calculated by the Scherer’s equation. The average size of nanoparticles nickel sulfide after five cycle of 

sorption was estimated apr. 1 nm. 

References 

1.   Narmina O. Balayeva, Ofeliya O. Askerova, Abdulsaid A. Azizov, Rasim M. Alosmanov, Goncha M. Eyvazova b, 

Mustafa B. Muradov, Composites: Part B 53 (2013) 391–394 polymer/elastomeric composites for their applications. 

2.   Wang J., Chew S.Y., Wexler D., Wang G. X., Ng, S.H., Zhong,S., Liu H.K., Electrochem. Commun.,  

3.   11. Kapinus E. I.; Viktorova T. I.; Khalyavka T. A. Theor. Exp. Chem., 42, 282 (2006)  

4.   Azizov AA, Alosmanov RM, Melikov AJ. In: Proceedings of the universities’ Chemistry and Chemical Engineering. 

Technology; 2003. Issue 6. p. 25–7.