SPbOPEN 2019
Journal of Physics: Conference Series
1410 (2019) 012230
IOP Publishing
doi:10.1088/1742-6596/1410/1/012230
2
PZT thin films with piezoelectric properties have a perovskite-type structure. The spontaneous electric
dipole moment of PZT films can be reoriented between certain crystallographically stable states using
appropriate levels of the electric field that do not lead to dielectric breakdown. In the perovskite
structure of ABO3, where A is a bivalent ion, B is a tetravalent ion, the cubic lattice may be distorted
at temperatures below the Curie temperature. These distortions shift the octahedrally oriented cations
from the center of the structure. Accordingly, a dipole moment is created between the center of the
negative charge created by the oxygen octahedron and the center of the positive charge created by the
cation sublattice. The shifts in the position of the A-ions of Pb
+2
, like the B-ions of Zr
+4
and Ti
+4
,
determine the properties of the PZT (ZrxTi1 - x) O
3
dipoles [10].
The values of the piezoelectric parameters of thin perovskite PZT films exceed the similar parameters
of AlN and ZnO. However, the stability of the characteristics of the piezoelectric parameters of polar
dielectrics is much higher and their production has been mastered much more widely, which in turn
imposes restrictions on the use of PZT films. For industrial production of thin piezoelectric PZT films,
a number of fundamental tasks are required to be solved: the development of the physical
fundamentals of the technology for manufacturing low-dimensional piezoelectric films; the study of
the features of the piezoelectric state and the switching mechanisms of spontaneous polarization; the
creation of conditions of the polarized state stable in time [5, 6, 11]. Moreover, the further integration
of piezoelectric perovskite films with used deposition modes with strain-resistant semiconductor
pressure sensors is limited by the high temperatures of sensitive elements production.
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