Poster presentation
153
LIPIDS OF Calligonum junceum
Sh.K. Khidoyatova
1
, N.K. Yuldasheva
1
, S.D. Gusakova
1
, S.G. Sherimbetov
2
,
S.Z. Nishanbaev
1
1) S.Yu. Yunusov Institute of the Chemistry of Plant Substances Academy of sciences of
the Republic of Uzbekistan st. Mirzo-Ulugbek, 77, 100170 Tashkent
e-mail: shaxnoza_karimova_80@mail.ru
2 )O.S.Sodikov Institute of Bioorganic Chemistry, Academy of Sciences of the
Republic of Uzbekistan
The species
C. junceum
L. is distributed in deserts and sandy steppes of North
Africa,
Western Siberia, Anterior and Central Asia. Tannins, phenol-carboxylic acids,
alkaloids, leucoanthocyanidins, flavonoids were found in the chemical composition of
the plant. The alkaloid kalligonin with hypotensive activity has
been isolated from the
herb
C. junceum
, phenolic carboxylic acids of the plant have a choleretic effect,
leucoanthocyanidins and a number of flavonoids exhibit antitumor activity.
For the first time, we studied the lipids of air-dry leaves of
C. junceum
collected in
2021 on the drained bottom of the Aral Sea. The yield of total lipids (TL) was 1.86% (of
leaf weight). TL was divided by the CC method on silicagel into neutral lipids (NL,
0.34%), glycolipids (GL, 1.27%) and phospholipids (PhL, 0.25%). According to TLC
data, sterylglycosides and esters of sterylglycosides predominated in GL, they were
accompanied by cerebrosides, di- and monohalactosyldiglycerides, chlorophyll
derivatives. Squalene, carotenoids, fatty acid esters (FA) with triterpenols and
phytosterols,
cyclic alcohol acetates, triacylglycerides, free FA, triterpenols and
phytosterols were found in the NL. phosphatidylethanolamines, phosphatidylcholines
(the main component), phosphatidic acid and phosphtidylinosites
were found in the
composition of PhL. The composition of FA lipids was determined by GC on an Agilent
GC 8860 chromatograph. (table).
Table. Fatty acid composition of lipids in the leaves of
C. junceum
,
GC, %, from the mass of
acids
Fatty acids
NL
GL
PhL
Fatty acids
NL
GL
PhL
10:0
3,34
0,80
0,40
18:2
4,7
4,07
8,68
12:0
12,13
6,43
1,20
20:0
-
2,18
0,71
14:0
4,41
4,46
1,27
22:0
2,18
6,17
0,64
16:0
36,80
40,40
52,10
24:0
2,65
3,42
0,73
17:0
-
0,81
-
26:0
2,36
3,26
-
18:0
9,44
9,40
8,26
Ʃ
saturated FA
73,31
77,33
66,56
18:1
20,41
16,66
22,81
Ʃ
unsaturated FA
26,69
22,67
33,44
trans
-18:1
3,89
1,34
1,95
The results show that saturated fatty acids predominate in all lipid groups (mainly
16:0), the amount of unsaturated FA ranges from 22.6 to 33.44%, with most of the
amount being 18:1 acid.
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