Energies
2022
,
15
, 7804
13 of 24
SNF/YMP
4
SNF
Stainless steel, Ni-
based alloy
-
HLW/YMP
Glass
Stainless steel
-
1
Morsleben;
2
Transuranic waste;
3
Waste Isolation Pilot Plant,;
4
Yucca Mountain Plant (Nevada).
SNF disposal at the YMP was halted during the Obama administration with Blue Ribbon Commis-
sion assigned and tasked with the development of a perspective for the NWM in the US.
Table 5.
Functions of the wasteform (immobilising matrix) and container components of EBS.
Country
Wasteform
Container
Belgium
10,000 y resistance to leaching
Facilitate handling
Canada
10,000 y radionuclide retention
100,000 y containment
Czech Republic
10,000 y radionuclide retention
500–1000 y containment
Finland
Slow
rate of release
100,000 y containment
France
100,000 y
resistance
Facilitate handling
Germany
1
Not part of EBS
Not part of EBS
Japan
>10,000 y containment and slow re-
lease
1000 y containment,
creating
reducing conditions
Korea
Resistance to leaching
1000 y containment
Spain
Slow rate of release
1000 y containment
Sweden (KBS-3)
Slow rate of release
100,000 y isolation
Switzerland
150,000 y low release
Initial period complete con-
tainment
UK (Nirex, RWM)
300–500 y limit release
300–500 y
physical integrity,
limit release
US
WIPP: Not part of EBS; YMP: reduce
release rate
WIPP: Not part of EBS; YMP:
>10,000 y
resistance to corro-
sion
1
Morsleben.
4.3. Delay of Radionuclide Release
The EBS of GDF has a finite lifetime and its role is to minimise and significantly delay
the release of radionuclides into the geological formation. Durable materials are therefore
preferred for EBS including the wasteform and container materials (see, e.g., Figure 6b).
Based on known corrosion rates of EBS materials in each specific case (
r
, m/y), it is possible
to estimate their lifetimes
t
EBS
from the equation
t
EBS
= L
EBS
/r
(5)
where
L
EBS
is the critical dimension of barrier, e.g., the wall thickness of the container (
10
mm) or vitreous wasteform block half-diameter (
20 cm). Figure 7
illustrates currently
available estimates of initial rates of corrosion and residual (steady state rates in saturated
conditions when the material is confined in contact with its corrosion products) of durable
ceramics, glasses, and corrosion-resistant metallic alloys [33].