Supervisor: Amir Reza Vakhshouri Key words: Biodiesel, transesterification, zeolite, clinoptilolite, heterogeneous basic
catalyst
Biodiesel is a renewable displacement fuel produced from vegetable oil,
restaurant greases, animal fat (in liquid form), or recycled cooking oil. As an
alternative energy source, it is widely used in diesel engines. The main
purpose of this research is to produce biodiesel from cooking oil with the
presence of homogenous and heterogeneous catalysts and to compare their
effect on the final product. Firstly, there are some key advantages of utilizing
biodiesel instead of petro-diesel such as:
its ability to improve the lubricating properties of petro-diesel when slightly
added
the economic viability of its large-scale production compared to
conventional fuels
greater safety ensured in storage and transportation caused by higher
flashing temperature for biodiesel (130
0
C) in comparison with petroleum
diesel (52
0
C) (Energy).
The principal reason that makes biodiesel one step ahead of conventional
energy sources for internal combustion engines is its environmental friendliness.
In terms of greenhouse gas emissions to the atmosphere, the amount of
unburned hydrocarbons, particularly carbon monoxide, is substantially reduced
up to 75% cleaner than petro-diesel made from fossil fuels (Biodiesel, 2014).
According to the U.S. Department of Energy, utilization of B100 fuels (pure
biodiesel) can cut carbon monoxide emissions and the matter which produces
smog almost in half. Moreover, biodiesel usage can lessen emissions of
hydrocarbon by from 75 up to 90 percent. Furthermore, the industrial
operations to produce biodiesel are cleaner than that for conventional diesel,
therefore emissions associated with the life cycle of the fuel are reduced by
more than 80%.
Transesterification is one of the biodiesel production processes that are
widely used. Organically derived oils mentioned above enter the reaction with
alcohol (commonly methanol) and are further chemically processed to